4-Methyl-N-(3-methylphenyl)benzenesulfonamide
نویسندگان
چکیده
In the title compound, C(14)H(15)NO(2)S, the conformation of the N-C bond in the C-SO(2)-NH-C segment has gauche torsion angles with respect to the S=O bonds. Further, the conformation of the N-H bond is anti to the 3-methyl group in the aniline benzene ring. The mol-ecule is bent at the N atom with a C-SO(2)-NH-C torsion angle of 56.7 (3)°. The dihedral angle between the benzene rings is 83.9 (1)°. In the crystal, inter-molecular N-H⋯O hydrogen bonds pack the mol-ecules into a supra-molecular structure.
منابع مشابه
4-Chloro-2-methyl-N-(3-methylphenyl)benzenesulfonamide
The N-H bond in the title compound, C(14)H(14)ClNO(2)S, the dihedral angle between the two benzene rings is 75.5 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.
متن کامل4-Chloro-N-(3-methylphenyl)benzenesulfonamide
In the crystal of the title compound, C(13)H(12)ClNO(2)S, the N-H bond is anti to the meta-methyl group in the aniline ring. The C-SO(2)-NH-C torsion angle is -57.6 (2)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 84.7 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.
متن کامل4-Chloro-2-methyl-N-(2-methylphenyl)benzenesulfonamide
In the crystal structure of the title compound, C(14)H(14)ClNO(2)S, the two aromatic rings are tilted relative to each other by 45.8 (1)°. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds occur.
متن کامل4-Methyl-N-(2-methylphenyl)benzenesulfonamide
In the title compound, C(14)H(15)NO(2)S, the dihedral angle between the aromatic rings is 49.7 (1)°. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds occur.
متن کاملN-Ethyl-4-methyl-N-(3-methylphenyl)benzenesulfonamide
The title compound, C(16)H(19)NO(2)S, crystallizes with two crystallographically independent mol-ecules in the asymmetric unit in which the dihedral angles between the planes defined by the aromatic rings are 35.3 (2) and 42.5 (2)°. In the crystal, inter-molecular C-H⋯O hydrogen bonds stabilize the packing.
متن کامل